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MTBE has been used in U.S. gasoline at low levels since 1979 to replace tetra-ethyl lead as an octane enhancer to help prevent the engine from "knocking." Since 1992, MTBE has been used at higher concentrations in some gasoline to fulfill the oxygenate requirements set by Congress in Clean Air Act amendments.
Recent state laws have been passed to ban MTBE in certain areas. Ethanol is being used over MTBE because of concerns of groundwater contamination. A table of state by state information is available here:
http://www.eia.doe.gov/oiaf/servicerpt/mtbeban/table1.html
Source
EPA MTBE FAQ webpage