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Spectroscopy

Spectroscopy is the study of spectra.

Originally a spectrum was what was observed when white light was dispersed through a prism. Soon the term referred to a plot of light intensity as a function of frequency or wavelength. Planck later realized that frequency represents electromagnetic energy.

E = h ν

Today the term has been generalized even further to include any data that are the result of a study where an energy (or frequency) is systematically varied

The recording and studying of spectrum of energy levels in atoms or molecules in the physical sciences is called spectroscopy. A device for recording a spectrum is a spectrometer or spectrophotometer. The latter term is used when an optical spectrum is recorded by the device.

Table of contents
1 Types of spectroscopy
2 Energy of photons
3 Kinetic energy of electrons
4 Kinetic energy of ions or molecules
5 Vibrational energy
6 Analysis with spectroscopy
7 Other Topics

Types of spectroscopy

There are many various branches of the study of spectra:

Energy of photons

Kinetic energy of electrons

Kinetic energy of ions or molecules

Vibrational energy

Analysis with spectroscopy

Analysis involves finding out absorbances of the analyte.

Analysis of a mixture

When there is more than one absorbing species in a solution, the absorbance at a particular wavelength is the sum of absorbances from all species at that wavelength.

A = εXb[X] + εYb[Y] + εZb[Z] + ...

The composition of a mixture of two or more compounds can be found by using two or more wavelengths and by knowing ε at each wavelength for each compound. These wavelengths are usually wavelengths of maximum absorption (absorbance maxima) for the individual components. For two components, two wavelengths give two equations:

A' = εXb[X] + εYb[Y]
A" = εXb[X] + εYb[Y]

Other Topics





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