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Gauss presented the theorem this way (translated from Latin):
You can't bend a piece of paper onto a sphere (more formally, the plane and the 2-sphere are not locally isometric). The follows immediately from the fact that the plane has Gaussian curvature 0 (at all points) while no point on a sphere always has Gaussian curvature 0. (It is, however, possible to prove this special case more directly.)
Corresponding points on the catenoid and the helicoid (two very different-looking surfaces) have the same Gaussian curvature. (The two surfaces are locally isometric.)
Some simple applications