On the December 21, 1803 at Coburg, she married (as his second wife) Karl, Fürst zu Leiningen (1763-1814) whose first wife Henriette Reuss zu Ebersdorf was her mother's sister. They had two children:
Carl Friedrich Wilhelm Emich (1804-1856)
Feodora (1807-1872)
On the May 29, 1818 at Coburg (and again on July 11, 1818 at Kew Palace) she married Edward Augustus, Duke of Kent (1767-1820). Their only child was: